“Near Perfect” Absorption of Sunlight, From All Angles
To harness the full spectrum of solar energy, Fresnel reflection at the surface of a solar cell must be eliminated over the entire solar spectrum and at all angles. Here, we show that a multilayer nanostructure having a graded-index profile (...) can accomplish a near-perfect transmission of all-color of sunlight. An ultralow total reflectance of 1%-6% has been achieved over a broad spectrum, λ=400to1600 nm, and a wide range of angles of incidence, θ=0°-60°. The measured angle- and wavelength-averaged total reflectance of 3.79% is the smallest ever reported in the literature, to our knowledge.


Typical antireflective coatings are engineered to transmit light of one particular wavelength. Lin’s new coating stacks seven of these layers, one on top of the other, in such a way that each layer enhances the antireflective properties of the layer below it. These additional layers also help to “bend” the flow of sunlight to an angle that augments the coating’s antireflective properties. This means that each layer not only transmits sunlight, it also helps to capture any light that may have otherwise been reflected off of the layers below it. The seven layers, each with a height of 50 nanometers to 100 nanometers, are made up of silicon dioxide and titanium dioxide nanorods positioned at an oblique angle — each layer looks and functions similar to a dense forest where sunlight is “captured” between the trees. The nanorods were attached to a silicon substrate via chemical vapor disposition, and Lin said the new coating can be affixed to nearly any photovoltaic materials for use in solar cells, including III-V multi-junction and cadmium telluride.